By combining scanning probe lithography with nanoreactor-mediated synthesis strategies, Pengcheng Chen established a highly versatile and precise method for synthesizing polyelemental nanoparticles, enabling high-throughput fabrication and study of nanomaterials libraries.
Utilizing scanning probe lithography, Pengcheng created polymer nanoreactor droplets containing metal ions. The spatial confinement of the nanoreactors facilitated the formation of polyelemental nanoparticles at very small scales. Using a five-element system of gold, silver, copper, cobalt, and nickel as a model, he successfully synthesized nanoparticles in all possible combinations of these five metals. This marks the first international achievement in database-style fabrication and combinatorial study of polyelemental nanoparticles, expanding the understanding of the thermodynamic behavior of multielement systems at the nanoscale.
Leveraging this technology, Pengcheng created a non-centrosymmetric heterojunction nanoparticle database encompassing seven elements. Through systematic exploration of the seven-element system combined with theoretical modeling, he successfully constructed one to six different thermodynamically stable phase boundaries within a single particle, providing theoretical guidance for the creation of nanomaterials with complex heterostructures.
This technology provides an ideal platform for the study of nanomaterials genomics and has the potential to become a new generation of transformative technology for the high-throughput screening of functional nanomaterials.