Carbon
dioxide and water are the main products of burning fossil fuels – our major
source of energy for power generation and transportation. Scientists are now
interested in its reverse process: artificial photosynthesis, which mimics natural
photosynthesis and uses sunlight to convert water and carbon dioxide back into
hydrogen, carbon monoxide, methane, and other fuels. As the main product of
solar splitting of water, hydrogen is the most ideal zero-emission fuel for
future vehicles with the highest energy density. And reduction of carbon
dioxide from the atmosphere is not only important for fuel production, but also
crucial to climate change mitigation.
However, to create a cost-effective chemical process that is not favored by the
conditions of the Earth, is always a challenging topic for chemists.
These are
the research fields in which Jingshan Luo achieved a series of important
breakthroughs.
In
photoelectrochemical water splitting, he developed high quality nanowire array
photocathode using low-cost materials and solved the incompatibility between
the absorption depth and electron transport length. By doing this, he realized
the highest solar to hydrogen conversion efficiency for oxide based solar water
splitting devices. For the first time, he
combined perovskite solar cells with nickel and iron based catalysts for solar
water splitting in photovoltaic driven electrolysis. Costing only a 1/5 to a 1/3 of tradition technology, Luo
achieved almost the same level of solar to hydrogen conversion efficiency
(12.3%) using only inexpensive materials. For CO2 reduction, he developed an
inexpensive and Earth-abundant CO2 reduction catalyst and achieved a record
solar to CO conversion efficiency of 13.4% at a very high selectivity (>90%).
All of the above breakthrough technologies are realized with inexpensive
materials, and they are very valuable to both the industry and academia.